Steps to remove make from a face using PSE :
1. Select Brush tool from tool bar.
2. Click on Alt on Windows and Option on MAC to activate eye dropper tool and select a color below the eyes having skin color and minimal makeup.
3. Choose the mode as 'Hue' or 'Color' from top bar and rub the tool around the eye area where makeup was applied.
Makeup is removed. You may try the same technique to remove makeup from other parts of face.
Here are the initial and the final photos :
